sec-Butyllithium | CAS:598-30-1
sec-Butyllithium
- Name:sec-Butyllithium
- CAS:598-30-1
- Synonyms:
- Molecular Formula:C4H9Li
- Molecular Weight:64.05
- EINESC:209-927-7
Description
Properties
Flash point | -17 ºC |
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Density | 0.769 |
Safety
Symbol(GHS) | F;C;N |
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Hazard Codes | R11;R15;R17;R34;R51/53;R65;R66;R |
SDS/MSDS | S16;S26;S33;S36/37/39;S43;S45;S6 |
SDS
Source | SDS/MSDS Samples |
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Alfa-Aesar | View & Download |
Synthetic Route
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Articles
Peer-Reviewed Papers
Simultaneous determination of aromatic acid metabolites of styrene and styrene-oxide in rat urine by gas chromatography-flame ionization detection.Frédéric Cosnier et al.Journal of analytical toxicology, 36(5), 312-318 (2012-04-12)
Insensitivity of the in vitro cytokinesis-block micronucleus assay with human lymphocytes for the detection of DNA damage present at the start of the cell culture.Günter Speit et al.Mutagenesis, 27(6), 743-747 (2012-08-08)
Evidence for DNA and protein binding by styrene and styrene oxide.D H Phillips et al.Critical reviews in toxicology, 24 Suppl, S35-S46 (1994-01-01)
Genotoxicity of styrene-7,8-oxide and styrene in Fisher 344 rats: a 4-week inhalation study.Laurent Gaté et al.Toxicology letters, 211(3), 211-219 (2012-04-18)
CYP2F2-generated metabolites, not styrene oxide, are a key event mediating the mode of action of styrene-induced mouse lung tumors.G Cruzan et al.Regulatory toxicology and pharmacology : RTP, 62(1), 214-220 (2011-11-02)
Metabolism and toxicity of styrene in microsomal epoxide hydrolase-deficient mice.Gary P Carlson Journal of toxicology and environmental health. Part A, 73(24), 1689-1699 (2010-11-09)
Surprising unreactivity of cholesterol-5,6-epoxides towards nucleophiles.Michael R Paillasse et al.Journal of lipid research, 53(4), 718-725 (2012-01-31)
Subtoxic product levels limit the epoxidation capacity of recombinant E. coli by increasing microbial energy demands.Daniel Kuhn et al.Journal of biotechnology, 163(2), 194-203 (2012-08-28)
Tandem metal-coordination copolymerization and organocatalytic ring-opening polymerization via water to synthesize diblock copolymers of styrene oxide/CO2 and lactide.Guang-Peng Wu et al.Journal of the American Chemical Society, 134(42), 17739-17745 (2012-09-29)
Comparison of styrene oxide enantiomers for hepatotoxic and pneumotoxic effects in microsomal epoxide hydrolase-deficient mice.Gary P Carlson Journal of toxicology and environmental health. Part A, 74(6), 347-350 (2011-01-29)
Semi-aromatic polyesters by alternating ring-opening copolymerisation of styrene oxide and anhydridesNejad EH, et al. Polym. Chem., 3(5), 1308-1313 (2012)
Characterization of the epoxide hydrolase NcsF2 from the neocarzinostatin biosynthetic gene cluster.Shuangjun Lin et al.Organic letters, 12(17), 3816-3819 (2010-08-14)
Absolute configuration assignment of (3-phenyloxirane-2,2-diyl)bis(phenylmethanone) via density functional calculations of optical rotation and vibrational circular dichroism.Alessandra Lattanzi et al.Chirality, 22 Suppl 1, E130-E135 (2010-11-03)
Identification and characterization of epoxide hydrolase activity of polycyclic aromatic hydrocarbon-degrading bacteria for biocatalytic resolution of racemic styrene oxide and styrene oxide derivatives.Jung-Hee Woo et al.Biotechnology letters, 35(4), 599-606 (2012-12-18)
Hepatotoxicity and pneumotoxicity of styrene and its metabolites in glutathione S-transferase-deficient mice.Gary P Carlson Drug and chemical toxicology, 34(4), 440-444 (2011-07-14)
Styrene oxide isomerase of Rhodococcus opacus 1CP, a highly stable and considerably active enzyme.Michel Oelschlägel et al.Applied and environmental microbiology, 78(12), 4330-4337 (2012-04-17)
Copper(II)-catalyzed hydrosilylation of ketones using chiral dipyridylphosphane ligands: highly enantioselective synthesis of valuable alcohols.Feng Yu et al.Chemistry (Weinheim an der Bergstrasse, Germany), 17(50), 14234-14240 (2011-11-09)
Highly selective synthesis of CO2 copolymer from styrene oxide.Wu GP, et al. Macromolecules, 43(21), 9202-9204 (2010)
Enantioselective hydrolysis of styrene oxide with the epoxide hydrolase of Sphingomonas sp. HXN-200Liu Z, et al. Tetrahedron Asymmetry, 17(1), 47-52 (2006)
Use of hydrophilic ionic liquids in a two-phase system to improve Mung bean epoxide hydrolases-mediated asymmetric hydrolysis of styrene oxide.Wen-Jing Chen et al.Journal of biotechnology, 162(2-3), 183-190 (2012-09-22)
Modification of the metabolism and toxicity of styrene and styrene oxide in hepatic cytochrome P450 reductase deficient mice and CYP2F2 deficient mice.Gary P Carlson Toxicology, 294(2-3), 104-108 (2012-03-06)
Laboratory evolution of an epoxide hydrolase - towards an enantioconvergent biocatalyst.Michael Kotik et al.Journal of biotechnology, 156(1), 1-10 (2011-08-23)
Engineered catalytic biofilms for continuous large scale production of n-octanol and (S)-styrene oxide.Rainer Gross et al.Biotechnology and bioengineering, 110(2), 424-436 (2012-08-14)
Solvent and TMEDA effects on the configurational stability of chiral lithiated aryloxiranes.Filippo Maria Perna et al.Chemistry (Weinheim an der Bergstrasse, Germany), 17(29), 8216-8225 (2011-05-28)
Synthesis of the anti-HIV agent (-)-hyperolactone C by using oxonium ylide formation-rearrangement.David M Hodgson et al.Chemistry (Weinheim an der Bergstrasse, Germany), 17(35), 9731-9737 (2011-07-19)
Production host selection for asymmetric styrene epoxidation: Escherichia coli vs. solvent-tolerant Pseudomonas.Daniel Kuhn et al.Journal of industrial microbiology & biotechnology, 39(8), 1125-1133 (2012-04-25)
Preparative-scale kinetic resolution of racemic styrene oxide by immobilized epoxide hydrolase.Deniz Yildirim et al.Enzyme and microbial technology, 49(6-7), 555-559 (2011-12-07)
Efficient asymmetric hydrolysis of styrene oxide catalyzed by Mung bean epoxide hydrolases in ionic liquid-based biphasic systems.Wen-Jing Chen et al.Bioresource technology, 115, 58-62 (2011-11-22)
Styrene-7,8-oxide. Report on carcinogens : carcinogen profiles, 12, 391-392 (2011-08-25)
Cloning and characterization of an epoxide hydrolase from Cupriavidus metallidurans-CH34.Ranjai Kumar et al.Protein expression and purification, 79(1), 49-59 (2011-04-26)
Remarks
Products protected by valid patents are not offered for sale in countries where the sale of such products constitutes a patent infringement and its liability is at buyer's risk.
Products currently covered by valid US Patents are offered for R&D use in accordance with 35 USC 271 +A13(1).
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