
Tolylene-2,4-diisocyanate | CAS:584-84-9
Tolylene-2,4-diisocyanate
- Name:Tolylene-2,4-diisocyanate
- CAS:584-84-9
- Synonyms:4-Methyl-1,3-phenylene diisocyanate; 2,4-Diisocyanatotoluene; TDI
- Molecular Formula:C9H6N2O2
- Molecular Weight:174.16
- EINESC:209-544-5
Description
Properties
Melting point | 12.5-13.5 ºC |
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Water Solubility | react |
Boiling point | 115-120 ºC (10 mmHg) |
Flash point | 127 ºC |
Density | 1.225 |
Refractive index | 1.567-1.569 |
Safety
Symbol(GHS) | T+ |
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Hazard Codes | R26;R36/37/38;R40;R42/43;R52/53 |
SDS/MSDS | S23;S36/37;S45;S61 |
SDS
Source | SDS/MSDS Samples |
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Alfa-Aesar | View & Download |
TCI | View & Download |
Synthetic Route
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More
Articles
Peer-Reviewed Papers
Asymmetric synthesis of (-)-aurantioclavine via palladium-catalyzed intramolecular allylic amination.Satoshi Suetsugu et al.Organic letters, 16(3), 996-999 (2014-01-28)
Palladium-catalyzed β arylation of carboxylic esters.Alice Renaudat et al.Angewandte Chemie (International ed. in English), 49(40), 7261-7265 (2010-08-21)
European Journal of Inorganic Chemistry, 6, 1262-1269 (2004)
The elusive structure of Pd2(dba)3. Examination by isotopic labeling, NMR spectroscopy, and X-ray diffraction analysis: synthesis and characterization of Pd2(dba-Z)3 complexes.Anant R Kapdi et al.Journal of the American Chemical Society, 135(22), 8388-8399 (2013-05-25)
Littke, A. F.; Dai, C.; Fu, G.C. Journal of the American Chemical Society, 122, 4020-4020 (2000)
Kawatsura, M.; Hartwig, J. F. Journal of the American Chemical Society, 121, 1473-1473 (1999)
Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.Xiaoqiang Shen et al.Journal of the American Chemical Society, 132(40), 14076-14078 (2010-09-23)
Palladium-catalyzed asymmetric synthesis of allylic fluorides.Matthew H Katcher et al.Journal of the American Chemical Society, 132(49), 17402-17404 (2010-11-23)
Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: The role of ligands.Michael J Ardolino et al.Tetrahedron, 71(37), 6409-6413 (2015-08-19)
Tris DBA Ameliorates Accelerated and Severe Lupus Nephritis in Mice by Activating Regulatory T Cells and Autophagy and Inhibiting the NLRP3 Inflammasome.Chung-Yao Wu et al.Journal of immunology (Baltimore, Md. : 1950), 204(6), 1448-1461 (2020-02-16)
Pd(0)-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-α-chloroacrylates.Martin Arthuis et al.Chemical communications (Cambridge, England), 46(41), 7810-7812 (2010-09-21)
Efficient syntheses of [¹¹C]zidovudine and its analogs by convenient one-pot palladium(0)-copper(I) co-mediated rapid C-[¹¹C]methylation.Zhouen Zhang et al.Journal of labelled compounds & radiopharmaceuticals, 57(8), 540-549 (2014-07-06)
Crystal and molecular structure of tris (dibenzylideneacetone) dipalladium (0).Pierpont CG and Mazza MC Inorganic Chemistry, 13(8), 1891-1895 (1974)
Wolfe, J. P.; Wagaw, S.; Buchwald, S. L. Journal of the American Chemical Society, 118, 7215-7215 (1996)
Carborane-derived local anesthetics are isomer dependent.George R Kracke et al.ChemMedChem, 10(1), 62-67 (2014-11-26)
Asymmetric synthesis of new beta,beta-difluorinated cyclic quaternary alpha-amino acid derivatives.Santos Fustero et al.Organic letters, 8(18), 4129-4132 (2006-08-25)
Tetrahedron Letters, 33, 4859-4859 (1992)
Chemistry (Weinheim An Der Bergstrasse, Germany), 12, 5657-5657 (2006)
Remarks
Products protected by valid patents are not offered for sale in countries where the sale of such products constitutes a patent infringement and its liability is at buyer's risk.
Products currently covered by valid US Patents are offered for R&D use in accordance with 35 USC 271 +A13(1).
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