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Pivalic acid | CAS:75-98-9
Pivalic acid
  • Name:Pivalic acid
  • CAS:75-98-9
  • Synonyms:Trimethylacetic acid; 2,2-Dimethylpropanoic acid; Neopentanoic acid
  • Molecular Formula:C5H10O2
  • Molecular Weight:102.13
  • EINESC:200-922-5

Description

Properties

Melting point 33-36 ºC
Water Solubility 25 g/L (20 ºC)
Boiling point 163-164 ºC
Flash point 63 ºC
Density 0.905

Safety

Symbol(GHS) C
Hazard Codes R21/22;R34
SDS/MSDS S26;S36/37/39;S45

SDS

Source SDS/MSDS Samples
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Synthetic Route
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Articles
Peer-Reviewed Papers
Vanadium-induced nucleophilic IPSO substitutions in a coordinated tetrachlorosemiquinone ring: formation of the chloranilate anion as a bridging ligand.Pabitra Baran Chatterjee et al.Inorganic chemistry, 48(3), 804-806 (2009-01-09) Application of pi-acceptors to the spectrophotometric determination of lisinopril in commercial dosage forms.Nafisur Rahman et al.Farmaco (Societa chimica italiana : 1989), 60(6-7), 605-611 (2005-06-04) Intermolecular hydrogen bond complexes by in situ charge transfer complexation of o-tolidine with picric and chloranilic acids.Moamen S Refat et al.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(3), 672-679 (2011-05-03) [Spectrophotometric and HPLC evaluation of ceftazidime stability].B Palade et al.Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi, 114(1), 260-265 (2010-06-01) Hydrogen bonding in two solid phases of phenazine-chloranilic acid (1/1) determined at 170 and 93 K.Kazuma Gotoh et al.Acta crystallographica. Section C, Crystal structure communications, 63(Pt 1), o17-o20 (2007-01-09) [Spectrophotometric determination of azithromycin by charge transfer reaction].Wei Huang et al.Guang pu xue yu guang pu fen xi = Guang pu, 26(5), 913-916 (2006-08-04) Spectrophotometric analysis of selective serotonin reuptake inhibitors based on formation of charge-transfer complexes with tetracyanoquinodimethane and chloranilic acid.Ibrahim A Darwish et al.Journal of AOAC International, 89(2), 326-333 (2006-04-28) [Fluorescence spectroscopy determination of lomefloxacin by charge transfer complex formation with chloranilic acid].Li-ming Du et al.Guang pu xue yu guang pu fen xi = Guang pu, 24(12), 1623-1625 (2005-04-15) A partial proton transfer in hydrogen bond O-H···O in crystals of anhydrous potassium and rubidium complex chloranilates.Nikola Biliškov et al.The journal of physical chemistry. A, 115(14), 3154-3166 (2011-03-25) Synthesis, structure, and magnetic properties of valence ambiguous dinuclear antiferromagnetically coupled cobalt and ferromagnetically coupled iron complexes containing the chloranilate(2-) and the significantly stronger coupling chloranilate(*3-) radical trianion.Kil Sik Min et al.Journal of the American Chemical Society, 129(8), 2360-2368 (2007-02-03) Spectrophotometric, FTIR and theoretical studies of the charge-transfer complexes between isoniazid (pyridine-4-carboxylic acid hydrazide) and the acceptors (p-chloranil, chloranilic acid and tetracyanoethylene) in acetonitrile, their association constants, thermodynamic properties and other related properties.Seema Bagchi Chattaraj et al.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 95, 637-647 (2012-05-15) Exploiting pi-acceptors for the determination of thyroid hormones (T3 and T4) using a single interface flow system.Cristina I C Silvestre et al.Talanta, 79(4), 1177-1180 (2009-07-21) Reductions by aquatitanium(II).Zhiyong Yang et al.Dalton transactions (Cambridge, England : 2003), (10)(10), 1781-1784 (2005-05-07) Molecular characterization of chloranilic acid degradation in Pseudomonas putida TQ07.Luis G Treviño-Quintanilla et al.Journal of microbiology (Seoul, Korea), 49(6), 974-980 (2011-12-29) Spectrophotometric determination of terfenadine in pharmaceutical preparations by charge-transfer reactions.Elmorsy Khaled Talanta, 75(5), 1167-1174 (2008-07-01) Oxidative double dehalogenation of tetrachlorocatechol by a bio-inspired CuII complex: formation of chloranilic acid.Pieter C A Bruijnincx et al.Chemistry (Weinheim an der Bergstrasse, Germany), 14(18), 5567-5576 (2008-05-02) Spin exchange effects on the physicochemical properties of tetraoxolene-bridged bimetallic complexes.Dong Guo et al.Inorganic chemistry, 46(8), 3257-3274 (2007-03-21) Spectroscopic characterization of charge-transfer complexes of morpholine with chloranilic and picric acids in organic media: crystal structure of bis(morpholinium 2,4,6-trinitrocyclohexanolate).Moamen S Refat et al.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 75(2), 745-752 (2009-12-19) Two-dimensional, conductive niobium and molybdenum metal-organic frameworks.Michael E Ziebel et al.Chemical science, 11(26), 6690-6700 (2020-09-22) Indirect flow-injection spectrophotometric determination of meloxicam, tenoxicam and piroxicam in pharmaceutical formulations.Idrees F Al-Momani Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 22(12), 1611-1614 (2006-12-13) Utility of certain sigma- and pi-acceptors for the spectrophotometric determination of ganciclovir in pharmaceutical formulations.Ayman A Gouda Talanta, 80(1), 151-157 (2009-09-29) Preparation and spectroscopic studies on charge-transfer complexes of 2,2'-bipyridine with picric and chloranilic acids.Said M Teleb et al.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62(1-3), 140-145 (2005-11-01) Temperature dependence of one-dimensional hydrogen bonding in morpholinium hydrogen chloranilate studied by 35Cl nuclear quadrupole resonance and multi-temperature X-ray diffraction.Yasuhiro Tobu et al.Physical chemistry chemical physics : PCCP, 14(35), 12347-12354 (2012-08-09) Spectrophotometric, Fourier transform infrared spectroscopic and theoretical studies of the charge-transfer complexes between methyldopa [(S)-2 amino-3-(3,4-dihydroxyphenyl)-2-methyl propanoic acid] and the acceptors (chloranilic acid, o-chloranil and dichlorodicyanobenzoquinone) in acetonitrile and their thermodynamic properties.K Sharma et al.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 92, 212-224 (2012-03-27) Spectroscopic and structural characterization of the charge-transfer interaction of N,N'-bis-alkyl derivatives of 1,4,6,8-naphthalenediimide with chloranilic and picric acids.Moamen S Refat et al.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 70(4), 907-915 (2007-11-21) Spectrophotometric determination of nizatidine and ranitidine through charge transfer complex formation.M Walash et al.Archives of pharmacal research, 27(7), 720-726 (2004-09-11)
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