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Methylenaminoacetonitrile | CAS:109-82-0
Methylenaminoacetonitrile
  • Name:Methylenaminoacetonitrile
  • CAS:109-82-0
  • Synonyms:N-Methylenaminoacetonitrile
  • Molecular Formula:C3H4N2
  • Molecular Weight:68.08
  • EINESC:203-709-5

Description

Properties

Melting point 127-130 ºC

Safety

Symbol(GHS) Xn
Hazard Codes R20/21/22;R36/37/38
SDS/MSDS S22;S26;S36/37/39

SDS

Source SDS/MSDS Samples
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Synthetic Route
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Articles
Peer-Reviewed Papers
Formation of bromochlorodibenzo-p-dioxins and dibenzofurans from the high-temperature oxidation of a mixture of 2-chlorophenol and 2-bromophenol.Catherine S Evans et al.Environmental science & technology, 40(9), 3036-3042 (2006-05-25) Nickel-catalyzed cross-coupling of bromophenols with Grignard reagents in the solid phase synthesis.H Park et al.Molecular diversity, 5(2), 57-60 (2002-02-28) NADPH oxidase mediated maneb- and paraquat-induced oxidative stress in rat polymorphs: Crosstalk with mitochondrial dysfunction.Smriti Shukla et al.Pesticide biochemistry and physiology, 123, 74-86 (2015-08-13) Improved approach for analyzing bromophenols in seafood using stable isotope dilution analysis in combination with SPME.Steve C Fuller et al.Journal of agricultural and food chemistry, 56(18), 8248-8254 (2008-08-30) The inhibitory effect of selenium nanoparticles on protein glycation in vitro.Shaoxuan Yu et al.Nanotechnology, 26(14), 145703-145703 (2015-03-19) Potential for carboxylation-dehydroxylation of phenolic compounds by a methanogenic consortium.J G Bisaillon et al.Canadian journal of microbiology, 39(7), 642-648 (1993-07-01) Enhancement of bromophenol levels in aquacultured silver seabream (Sparus sarba).Wing Chi Joyce Ma et al.Journal of agricultural and food chemistry, 53(6), 2133-2139 (2005-03-17) Removal of bromophenols from water using industrial wastes as low cost adsorbents.Amit Bhatnagar Journal of hazardous materials, 139(1), 93-102 (2006-08-30) Simultaneous quantification of multiple classes of phenolic compounds in blood plasma by liquid chromatography-electrospray tandem mass spectrometry.Hong Chang et al.Journal of chromatography. A, 1217(4), 506-513 (2009-12-17) Synthesis of polybrominated diphenyl ethers via symmetrical tetra- and hexabrominated diphenyliodonium salts.Daniel Teclechiel et al.Chemosphere, 74(3), 421-427 (2008-11-11) Decomposition of 2-bromophenol in NaOH solution at high temperature.Miho Uchida et al.Journal of hazardous materials, 101(3), 231-238 (2003-08-26) Diindole-annulated naphthalene diimides: synthesis and optical and electronic properties of syn- and anti-isomers.Sabin-Lucian Suraru et al.The Journal of organic chemistry, 79(1), 128-139 (2013-11-28) Mechanisms of dioxin formation from the high-temperature oxidation of 2-bromophenol.Catherine S Evans et al.Environmental science & technology, 39(7), 2128-2134 (2005-05-06) Rotavirus increases levels of lipidated LC3 supporting accumulation of infectious progeny virus without inducing autophagosome formation.Francesca Arnoldi et al.PloS one, 9(4), e95197-e95197 (2014-04-17) Study of the photodegradation of 2-bromophenol under UV and sunlight by spectroscopic, chromatographic and chemometric techniques.Anusha Jayaraman et al.Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 910, 138-148 (2012-04-24) One-pot synthesis of benzofurans via palladium-catalyzed enolate arylation with o-bromophenols.Christian Eidamshaus et al.Organic letters, 10(19), 4211-4214 (2008-08-30) Acute and subacute nephrotoxicity of 2-bromophenol in rats.Elzbieta Bruchajzer et al.Toxicology letters, 134(1-3), 245-252 (2002-08-23) Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk).Giulia Caron et al.Journal of medicinal chemistry, 48(9), 3269-3279 (2005-04-29) Pathways of formation of 2-, 3- and 4-bromophenol from bromobenzene. Proposed mechanism for C-S lyase reactions of cysteine conjugates.K Lertratanangkoon et al.Research communications in chemical pathology and pharmacology, 80(3), 259-282 (1993-06-01) Tamoxifen in combination with temozolomide induce a synergistic inhibition of PKC-pan in GBM cell lines.Joana Balça-Silva et al.Biochimica et biophysica acta, 1850(4), 722-732 (2015-01-03) Development of a FRET biosensor with high specificity for Akt.Haruko Miura et al.Cell structure and function, 39(1), 9-20 (2013-11-12) Time-dependent effects of hydrophobic amine-containing drugs on lysosome structure and biogenesis in cultured human fibroblasts.Randall Logan et al.Journal of pharmaceutical sciences, 103(10), 3287-3296 (2014-07-22) Biodegradation of brominated aromatics by cultures and laccase of Trametes versicolor.B Uhnáková et al.Chemosphere, 76(6), 826-832 (2009-05-16) Developing structure-activity relationships for the prediction of hepatotoxicity.Nigel Greene et al.Chemical research in toxicology, 23(7), 1215-1222 (2010-06-18) Cellular apoptosis and cytotoxicity of phenolic compounds: a quantitative structure-activity relationship study.Cynthia D Selassie et al.Journal of medicinal chemistry, 48(23), 7234-7242 (2005-11-11) Seasonal distribution of bromophenols in selected Hong Kong seafood.Hau Yin Chung et al.Journal of agricultural and food chemistry, 51(23), 6752-6760 (2003-10-30) Discovery and mapping of genomic regions governing economically important traits of Basmati rice.Lakshminarayana R Vemireddy et al.BMC plant biology, 15, 207-207 (2015-08-22) Synthesis of dibenzofurans directly from aryl halides and ortho-bromophenols via one-pot consecutive SNAr and intramolecular palladium-catalyzed aryl-aryl coupling reactions.Hui Xu et al.Chemical & pharmaceutical bulletin, 56(10), 1496-1498 (2008-10-02) A predictive ligand-based Bayesian model for human drug-induced liver injury.Sean Ekins et al.Drug metabolism and disposition: the biological fate of chemicals, 38(12), 2302-2308 (2010-09-17) cIEF for rapid pKa determination of small molecules: a proof of concept.Stéphanie Romand et al.European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 63, 14-21 (2014-07-06) Mechanism and direct kinetics study on the homogeneous gas-phase formation of PBDD/Fs from 2-BP, 2,4-DBP, and 2,4,6-TBP as precursors.Wanni Yu et al.Environmental science & technology, 45(5), 1917-1925 (2011-02-12) Surface-mediated formation of polybrominated dibenzo-p-dioxins and dibenzofurans from the high-temperature pyrolysis of 2-bromophenol on a CuO/silica surface.Catherine S Evans et al.Environmental science & technology, 39(13), 4857-4863 (2005-08-02) Distribution of bromophenols in species of marine polychaetes and bryozoans from eastern Australia and the role of such animals in the flavor of edible ocean fish and prawns (shrimp).F B Whitfield et al.Journal of agricultural and food chemistry, 47(11), 4756-4762 (1999-12-20) Comparative proteomic analysis of extracellular proteins expressed by various clonal types of Staphylococcus aureus and during planktonic growth and biofilm development.Salman S Atshan et al.Frontiers in microbiology, 6, 524-524 (2015-06-20) Development and evaluation of methods for starch dissolution using asymmetrical flow field-flow fractionation. Part I: Dissolution of amylopectin.Daysi Perez-Rea et al.Analytical and bioanalytical chemistry, 407(15), 4315-4326 (2015-05-01) Detection and characterization of a dehalogenating microorganism by terminal restriction fragment length polymorphism fingerprinting of 16S rRNA in a sulfidogenic, 2-bromophenol-utilizing enrichment.Donna E Fennell et al.Applied and environmental microbiology, 70(2), 1169-1175 (2004-02-10) Changes in protein expression in two cholangiocarcinoma cell lines undergoing formation of multicellular tumor spheroids in vitro.Carlo Mischiati et al.PloS one, 10(3), e0118906-e0118906 (2015-03-11) Mechanisms of dioxin formation from the high-temperature pyrolysis of 2-bromophenol.Catherine S Evans et al.Environmental science & technology, 37(24), 5574-5580 (2004-01-14) Formation of bromochlorodibenzo-p-dioxins and furans from the high-temperature pyrolysis of a 2-chlorophenol/2-bromophenol mixture.Catherine S Evans et al.Environmental science & technology, 39(20), 7940-7948 (2005-11-22) Surface-mediated formation of PBDD/Fs from the high-temperature oxidation of 2-bromophenol on a CuO/silica surface.Catherine S Evans et al.Chemosphere, 63(8), 1291-1299 (2005-11-22) Molecular structures and properties of the complete series of bromophenols: Density functional theory calculations.Jun Han et al.The journal of physical chemistry. A, 109(23), 5186-5192 (2006-07-13)
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